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<h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">Rubidiumtriiodid</span></h1>
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<div id="mw-content-text" class="mw-body-content mw-content-ltr" lang="de" dir="ltr"><div class="mw-content-ltr mw-parser-output" lang="de" dir="ltr"><table class="wikitable infobox float-right" id="Vorlage_Infobox_Chemikalie" style="font-size:90%; margin-top:0; width:350px;" summary="Infobox Chemikalie">

<tbody><tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Kristallstruktur
</th></tr>
<tr>
<td colspan="2" class="hintergrundfarbe-basis" style="text-align:center;"><span typeof="mw:File"></span>
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<tr>
<td colspan="2" style="text-align:center; font-size:80%;"><span style="background:#C0C0C0;border-radius: 12px;color: transparent; width: 12px; line-height:12px;display:inline-block;">_</span> <a href="Rubidium" title="Rubidium">Rb</a><sup>+</sup> <span style="visibility:hidden;">0</span> <span style="background:#FF00FF;border-radius: 12px;color: transparent; width: 12px; line-height:12px;display:inline-block;">_</span> <a href="Iod" title="Iod">I</a><sup>1/3−</sup>
</td></tr>
<tr>
<td><a href="Kristallsystem" title="Kristallsystem">Kristallsystem</a>
</td>
<td>
<p>orthorhombisch
</p>
</td></tr>
<tr>
<td><a href="Raumgruppe" title="Raumgruppe">Raumgruppe</a>
</td>
<td>
<p><i>Pnma</i> (Nr. 62)<span style="display:none;">Vorlage:Raumgruppe/62</span><span class="editoronly" style="display:none;"></span>
</p>
</td></tr>
<tr>
<td><a href="Gitterparameter" title="Gitterparameter">Gitterparameter</a>
</td>
<td>
<p>a&nbsp;=&nbsp;1090,8&nbsp;pm, b&nbsp;=&nbsp;665,5&nbsp;pm, c&nbsp;=&nbsp;971,1&nbsp;pm
</p>
</td></tr>


<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Allgemeines
</th></tr>
<tr>
<td style="width:33%;">Name
</td>
<td>Rubidiumtriiodid
</td></tr>


<tr>
<td><a href="Verh%C3%A4ltnisformel" title="Verhältnisformel">Verhältnisformel</a>
</td>
<td>RbI<sub>3</sub>
</td></tr>
<tr>
<td>Kurzbeschreibung
</td>
<td>
<p>schwarze, glänzende Kristalle<sup id="cite_ref-Lax_1-0" class="reference"><a href="#cite_note-Lax-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Externe Identifikatoren/Datenbanken
</th></tr>
<tr>
<td colspan="2" style="padding:0;">
<table class="mw-collapsible mw-collapsed wikitable" data-expandtext="+" data-collapsetext="−" style="border-top:none; margin:-1px; width:calc(100% + 2px);">

<tbody><tr>
<td style="width:33%;"><a href="CAS-Nummer" title="CAS-Nummer">CAS-Nummer</a>
</td>
<td><span title="Untervorlage eingebunden: CASRN"></span><span class="KeinCASLink" title="CAS-Nummer ohne Common-Chemistry-Eintrag">12298-69-0</span><span class="editoronly" style="display:none;"></span>
</td>
<td style="background:#FFDEAD; color:#202122; border-top:1px solid #FFDEAD; padding:0.2em 0; vertical-align:bottom; width:5%;">
</td></tr>





<tr style="display:none;" class="editoronly">
<td><a href="PubChem" title="PubChem">PubChem</a>
</td>
<td colspan="2"><span class="wikidata-content"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/23717888">23717888</a></span>
</td></tr>




<tr>
<td style="border-right:1px solid #a2a9b1;"><a href="Wikidata" title="Wikidata">Wikidata</a>
</td>
<td colspan="2"><a href="https://www.wikidata.org/wiki/Q1651653" class="extiw external" title="d:Q1651653">Q1651653</a>
</td></tr></tbody></table>
</td></tr>








<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Eigenschaften
</th></tr>
<tr>
<td><a href="Molare_Masse" title="Molare Masse">Molare Masse</a>
</td>
<td>466,18&nbsp;<a href="Gramm" title="Gramm">g</a>·<a href="Mol" title="Mol">mol</a><sup>−1</sup>
</td></tr>
<tr>
<td><a href="Aggregatzustand" title="Aggregatzustand">Aggregatzustand</a>
</td>
<td>
<p>fest
</p>
</td></tr>
<tr>
<td><a href="Dichte" title="Dichte">Dichte</a>
</td>
<td>
<p>4,03&nbsp;g·cm<sup>−3</sup><sup id="cite_ref-Lax_1-1" class="reference"><a href="#cite_note-Lax-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>
<tr>
<td><a href="Schmelzpunkt" title="Schmelzpunkt">Schmelzpunkt</a>
</td>
<td>
<p>192&nbsp;<a href="Grad_Celsius" title="Grad Celsius">°C</a><sup id="cite_ref-Lax_1-2" class="reference"><a href="#cite_note-Lax-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>








<tr>
<td><a href="L%C3%B6slichkeit" title="Löslichkeit">Löslichkeit</a>
</td>
<td>
<p>leicht löslich in Wasser<sup id="cite_ref-Lax_1-3" class="reference"><a href="#cite_note-Lax-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</p>
</td></tr>




<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Sicherheitshinweise
</th></tr>


<tr>
<td colspan="2">
<table cellspacing="0" cellpadding="2" style="width:100%;">




<tbody><tr>
<td colspan="2" style="text-align:center"><b><a href="Global_harmonisiertes_System_zur_Einstufung_und_Kennzeichnung_von_Chemikalien" title="Global harmonisiertes System zur Einstufung und Kennzeichnung von Chemikalien">GHS-Gefahrstoffkennzeichnung</a></b><br><i>keine Einstufung verfügbar</i><sup id="cite_ref-NV_2-0" class="reference"><a href="#cite_note-NV-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup>
</td></tr></tbody></table>
</td></tr>












<tr>
<td colspan="2" style="background:#FFDEAD; color:#202122; font-size:80%; text-align:center; line-height:150%; padding:.25em;">Wenn nicht anders vermerkt, gelten die angegebenen Daten bei <a href="Standardbedingungen" title="Standardbedingungen">Standardbedingungen</a> (0 °C, 1000&nbsp;hPa).
</td></tr></tbody></table><p><span class="editoronly" style="display:none;"></span>
</p><p><b>Rubidiumtriiodid</b> ist eine <a href="Chemische_Verbindung" title="Chemische Verbindung">chemische Verbindung</a> aus den Elementen <a href="Rubidium" title="Rubidium">Rubidium</a> und <a href="Iod" title="Iod">Iod</a>.
</p>

<div class="mw-heading mw-heading2"><h2 id="Herstellung">Herstellung</h2></div>
<p>Rubidiumtriiodid wird aus <a href="Rubidiumiodid" title="Rubidiumiodid">Rubidiumiodid</a> und elementarem Iod in wässriger Lösung durch Erwärmen hergestellt.<sup id="cite_ref-Wells_3-0" class="reference"><a href="#cite_note-Wells-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup>
</p>
<dl><dd><span class="mwe-math-element mwe-math-element-inline"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\ce {RbI + I2 -> RbI3}}}">
<semantics>
<mrow class="MJX-TeXAtom-ORD">
<mstyle displaystyle="true" scriptlevel="0">
<mrow class="MJX-TeXAtom-ORD">
<mtext>RbI</mtext>
<mo>+</mo>
<msubsup>
<mtext>I</mtext>
<mrow class="MJX-TeXAtom-ORD">
<mn>2</mn>
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<mrow class="MJX-TeXAtom-ORD">
<mspace width="0pt" height="0pt" depth=".2em"></mspace>
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</msubsup>
<mo stretchy="false">⟶<!-- ⟶ --></mo>
<msubsup>
<mtext>RbI</mtext>
<mrow class="MJX-TeXAtom-ORD">
<mn>3</mn>
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<mrow class="MJX-TeXAtom-ORD">
<mspace width="0pt" height="0pt" depth=".2em"></mspace>
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</mrow>
<annotation encoding="application/x-tex">{\displaystyle {\ce {RbI + I2 -&gt; RbI3}}}</annotation>
</semantics>
</math></span><img src="./_assets_/eb734a37dd21ce173a46342d1cc64c92/88788af360f3ca78a5f902833a1a76f3acb7c1a6.svg" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.005ex; width:18.57ex; height:2.843ex;" alt="{\displaystyle {\mathrm {RbI} {}+{}\mathrm {I} {\vphantom {A}}_{\smash[{t}]{2}}{}\mathrel {\longrightarrow } {}\mathrm {RbI} {\vphantom {A}}_{\smash[{t}]{3}}}}" loading="lazy"></span></dd></dl>
<div class="mw-heading mw-heading2"><h2 id="Eigenschaften">Eigenschaften</h2></div>
<div class="mw-heading mw-heading3"><h3 id="Physikalische_Eigenschaften">Physikalische Eigenschaften</h3></div>
<p>Rubidiumtriiodid kristallisiert im <a href="Orthorhombisches_Kristallsystem" title="Orthorhombisches Kristallsystem">orthorhombischen</a> Kristallsystem mit der <a href="Raumgruppe" title="Raumgruppe">Raumgruppe</a> <i>Pnma</i> (Raumgruppen-Nr. 62)<span style="display:none;">Vorlage:Raumgruppe/62</span><span class="editoronly" style="display:none;"></span> und den <a href="Gitterparameter" title="Gitterparameter">Gitterparametern</a> a&nbsp;=&nbsp;1090,8&nbsp;pm, b&nbsp;=&nbsp;665,5&nbsp;pm und c&nbsp;=&nbsp;971,1&nbsp;pm, in der <a href="Elementarzelle" title="Elementarzelle">Elementarzelle</a> befinden sich vier <a href="Formeleinheit" title="Formeleinheit">Formeleinheiten</a>. Die Kristallstruktur ist <a href="Strukturtyp#Isotypie" title="Strukturtyp">isotyp</a> mit Caesiumtriiodid.<sup id="cite_ref-Tebbe_4-0" class="reference"><a href="#cite_note-Tebbe-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup>
Beim Erhitzen auf 270&nbsp;°C zersetzt sich das Rubidiumtriiodid in Rubidiumiodid und elementares Iod.<sup id="cite_ref-Wells_3-1" class="reference"><a href="#cite_note-Wells-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> Rubidiumtriiodid ist in <a href="Ethanol" title="Ethanol">Ethanol</a> löslich, in <a href="Diethylether" title="Diethylether">Ether</a> findet eine Zersetzung statt.<sup id="cite_ref-Wells_3-2" class="reference"><a href="#cite_note-Wells-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading3"><h3 id="Chemische_Eigenschaften">Chemische Eigenschaften</h3></div>
<p>Es wurde lange Zeit angenommen, dass Rubidiumtriiodid mit Iod zu höheren Polyiodiden RbI<sub>7</sub> und RbI<sub>9</sub> weiterreagiert.<sup id="cite_ref-Hamburger_5-0" class="reference"><a href="#cite_note-Hamburger-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> Dies wurde jedoch durch neuere Forschungen widerlegt.<sup id="cite_ref-Briggs_6-0" class="reference"><a href="#cite_note-Briggs-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Tebbe_4-1" class="reference"><a href="#cite_note-Tebbe-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup>
</p>
<div class="mw-heading mw-heading2"><h2 id="Einzelnachweise">Einzelnachweise</h2></div>
<ol class="references">
<li id="cite_note-Lax-1"><span class="mw-cite-backlink">↑ <sup><a href="#cite_ref-Lax_1-0">a</a></sup> <sup><a href="#cite_ref-Lax_1-1">b</a></sup> <sup><a href="#cite_ref-Lax_1-2">c</a></sup> <sup><a href="#cite_ref-Lax_1-3">d</a></sup></span> <span class="reference-text">Jean D’Ans, Ellen Lax: <i>Taschenbuch für Chemiker und Physiker. 3. Elemente, anorganische Verbindungen und Materialien, Minerale, Band 3.</i> 4. Auflage, Springer, 1997, ISBN 978-3-540-60035-0, S. 688 (<a rel="nofollow" class="external text" href="https://books.google.de/books?id=oWjEKDnsJgEC&amp;pg=PA688#v=onepage">eingeschränkte Vorschau</a> in der Google-Buchsuche).</span>
</li>
<li id="cite_note-NV-2"><span class="mw-cite-backlink"><a href="#cite_ref-NV_2-0">↑</a></span> <span class="reference-text">Dieser Stoff wurde in Bezug auf seine Gefährlichkeit entweder noch nicht eingestuft oder eine verlässliche und zitierfähige Quelle hierzu wurde noch nicht gefunden.</span>
</li>
<li id="cite_note-Wells-3"><span class="mw-cite-backlink">↑ <sup><a href="#cite_ref-Wells_3-0">a</a></sup> <sup><a href="#cite_ref-Wells_3-1">b</a></sup> <sup><a href="#cite_ref-Wells_3-2">c</a></sup></span> <span class="reference-text">HL. Wells, H. L. Wheele: <cite style="font-style:italic">Über Trihalogenverbindungen des Rubidiums und Kaliums</cite>. In: <cite style="font-style:italic"><a href="Zeitschrift_f%C3%BCr_anorganische_Chemie" class="mw-redirect" title="Zeitschrift für anorganische Chemie">Zeitschrift für anorganische Chemie</a></cite>. <span style="white-space:nowrap">Band<span style="display:inline-block;width:.2em">&nbsp;</span>1</span>, 1892, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em">&nbsp;</span>442<span style="display:inline-block;width:.2em">&nbsp;</span>ff</span>., <a href="Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1002/zaac.18920010140">10.1002/zaac.18920010140</a></span> (<a rel="nofollow" class="external text" href="http://www.archive.org/stream/zeitschriftfura31unkngoog#page/n451/mode/1up">Volltext</a>).<span class="Z3988" title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rfr_id=info:sid/de.wikipedia.org:Rubidiumtriiodid&amp;rft.atitle=%C3%9Cber+Trihalogenverbindungen+des+Rubidiums+und+Kaliums&amp;rft.au=L.+Wells%2C+H.+L.+Wheele&amp;rft.btitle=Zeitschrift+f%C3%BCr+anorganische+Chemie&amp;rft.date=1892&amp;rft.doi=10.1002%2Fzaac.18920010140&amp;rft.genre=book&amp;rft.pages=442ff&amp;rft.volume=1" style="display:none">&nbsp;</span></span>
</li>
<li id="cite_note-Tebbe-4"><span class="mw-cite-backlink">↑ <sup><a href="#cite_ref-Tebbe_4-0">a</a></sup> <sup><a href="#cite_ref-Tebbe_4-1">b</a></sup></span> <span class="reference-text">K. F. Tebbe, U. Georgy: <cite style="font-style:italic">Die Kristallstrukturen von Rubidiumtriiodid und Thalliumtriiodid</cite>. In: <cite style="font-style:italic"><a href="Acta_Crystallographica" title="Acta Crystallographica">Acta Crystallographica</a> Section C</cite>. <span style="white-space:nowrap">Band<span style="display:inline-block;width:.2em">&nbsp;</span>42</span>, <span style="white-space:nowrap">Nr.<span style="display:inline-block;width:.2em">&nbsp;</span>12</span>, Dezember 1986, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em">&nbsp;</span>1675–1678</span>, <a href="Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1107/S0108270186090972">10.1107/S0108270186090972</a></span>.<span class="Z3988" title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&amp;rfr_id=info:sid/de.wikipedia.org:Rubidiumtriiodid&amp;rft.atitle=Die+Kristallstrukturen+von+Rubidiumtriiodid+und+Thalliumtriiodid&amp;rft.au=K.+F.+Tebbe%2C+U.+Georgy&amp;rft.date=1986-12&amp;rft.doi=10.1107%2FS0108270186090972&amp;rft.genre=journal&amp;rft.issue=12&amp;rft.jtitle=Acta+Crystallographica+Section+C&amp;rft.pages=1675-1678&amp;rft.volume=42" style="display:none">&nbsp;</span></span>
</li>
<li id="cite_note-Hamburger-5"><span class="mw-cite-backlink"><a href="#cite_ref-Hamburger_5-0">↑</a></span> <span class="reference-text">Anna Hamburger, R. Abegg: <cite style="font-style:italic">Über die festen Polyjodide der Alkalien, ihre Stabilität und Existenzbedingungen bei 25 °C</cite>. In: <cite style="font-style:italic">Zeitschrift für Anorganische Chemie</cite>. <span style="white-space:nowrap">Band<span style="display:inline-block;width:.2em">&nbsp;</span>50</span>, <span style="white-space:nowrap">Nr.<span style="display:inline-block;width:.2em">&nbsp;</span>1</span>, 1906, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em">&nbsp;</span>403–438</span>, <a href="Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1002/zaac.19060500136">10.1002/zaac.19060500136</a></span> (<a rel="nofollow" class="external text" href="http://www.archive.org/stream/zeitschriftfura60unkngoog#page/n449/mode/2up">Volltext</a>).<span class="Z3988" title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&amp;rfr_id=info:sid/de.wikipedia.org:Rubidiumtriiodid&amp;rft.atitle=%C3%9Cber+die+festen+Polyjodide+der+Alkalien%2C+ihre+Stabilit%C3%A4t+und+Existenzbedingungen+bei+25+%C2%B0C&amp;rft.au=Anna+Hamburger%2C+R.+Abegg&amp;rft.date=1906&amp;rft.doi=10.1002%2Fzaac.19060500136&amp;rft.genre=journal&amp;rft.issue=1&amp;rft.jtitle=Zeitschrift+f%C3%BCr+Anorganische+Chemie&amp;rft.pages=403-438&amp;rft.volume=50" style="display:none">&nbsp;</span></span>
</li>
<li id="cite_note-Briggs-6"><span class="mw-cite-backlink"><a href="#cite_ref-Briggs_6-0">↑</a></span> <span class="reference-text">T. R. Briggs, E. S. Patterson: <cite style="font-style:italic">The Polyiodides of Rubidium</cite>. In: <cite style="font-style:italic"><a href="The_Journal_of_Physical_Chemistry" class="mw-redirect" title="The Journal of Physical Chemistry">The Journal of Physical Chemistry</a></cite>. <span style="white-space:nowrap">Band<span style="display:inline-block;width:.2em">&nbsp;</span>36</span>, <span style="white-space:nowrap">Nr.<span style="display:inline-block;width:.2em">&nbsp;</span>10</span>, 1932, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em">&nbsp;</span>2621–2624</span>, <a href="Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1021/j150340a011">10.1021/j150340a011</a></span> (<a rel="nofollow" class="external text" href="http://gallica.bnf.fr/ark:/12148/bpt6k92041w/f95.pagination.r=rubidium.langEN">Volltext</a>).<span class="Z3988" title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&amp;rfr_id=info:sid/de.wikipedia.org:Rubidiumtriiodid&amp;rft.atitle=The+Polyiodides+of+Rubidium&amp;rft.au=T.+R.+Briggs%2C+E.+S.+Patterson&amp;rft.date=1932&amp;rft.doi=10.1021%2Fj150340a011&amp;rft.genre=journal&amp;rft.issue=10&amp;rft.jtitle=The+Journal+of+Physical+Chemistry&amp;rft.pages=2621-2624&amp;rft.volume=36" style="display:none">&nbsp;</span></span>
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